生物化工专题数据库-----纳米材料

 

[篇名]

聚苯胺/氮化铬纳米复合材料的制备及表征

[著者]

陆元; 张祺

[机构]

东华大学材料科学与工程学院,上海 201620

[中文关键词]

聚苯胺; 氮化铬; 纳米复合材料; 电导率

[外文关键词]

PANI; CrN; nanocomposite; conductivity

[分类号]

 TQ342.83

[刊名]

现代化工

[出版时间]

20082

[来源]

 VOL28,NO.2._54—55

[中文摘要]

以纳米氧化铬(Cr2O3)为原料,采用氨气氮化法制备了纳米氮化铬(CrN)粉体。通过原位聚合的方法,在冰水浴中制得CrN/聚苯胺(PANI)纳米复合材料。纳米CrN掺杂的聚苯胺电导率较聚苯胺提高了一个数量级,较文献报道TiN/PANI高一个数量级。

[外文摘要]

Nano-sized CrN powder is prepared by the direct nitridation method from nano Cr2O3 powder,and polyaniline(PANI)/CrN nanocomposite with core-shell structure is prepared by in-situ chemical polymerization in ice bath,then characterized.The conductivity of the PANI/CrN nanocomposite doubles compared to that of pure PANI and PANI/TiN nanocomposite reported in documents.